Seo, Seung Woo published the artcileMicroreactor mediated deoxygenation of benzylic alcohols in a biphasic organic-aqueous medium, Application of Bis(4-fluorophenyl)methane, the publication is Tetrahedron Letters (2015), 56(21), 2795-2798, database is CAplus.
Safe and efficient deoxygenation of benzylic alcs. was accomplished using a droplet-based microreactor, which induced rapid mixing of the hydrophilic reagents (HI and H3PO2) in the aqueous phase and the alcs. in the organic phase. We investigated the relationship between the surface-to-volume ratio of the organic droplets and the reaction rate, and examined the effect of temperature and concentration of HI and H3PO2 in the reaction. The deoxygenated product was separated from the strongly acidic aqueous solution, and HI in the aqueous solution could be recycled. The reaction afforded 99% yield at 120 ¡ãC with HI (3.4 M HI) and H3PO2 (4.8 M).
Tetrahedron Letters published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C6H3BF4O2, Application of Bis(4-fluorophenyl)methane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia