Thoke, Mahesh Bhagwan published the artcileUnimolecular cooperative metallaphotocatalysis with conjugately bridged Ir-Ni complexes and its applications in organic coupling reactions, Safety of 2-Methylbenzoic acid, the publication is Organic Chemistry Frontiers (2022), 9(7), 1797-1807, database is CAplus.
Recent advances successfully upgraded the unique cooperative partnership between two distinct metals in photocatalysis. Herein we report the design, synthesis and comprehensive study of a series of heteroleptic Ir(III) complexes with a pendant binding site for nickel. The neutral Ir¡¤Lpytz complexes are apt to generate a novel unimol. Ir-Ni bimetallic system in situ during photocatalytic organic transformations where the pyridyl triazole ligand (Lpytz) acts as the conjugated bridge between Ir and Ni metal centers. A comparative study revealed that the bimetallic unimol. system with a conjugated linker is a convenient alternative to a bimol. system. UV-visible and photoluminescence quenching studies showed the importance of the conjugated bridging ligand to vectorial transfer of electrons from the photosensitizer unit to the reaction site. All novel Ir¡¤Lpytz complexes were evaluated in three challenging, mechanistically distinct photoinduced cross-coupling reactions (C-O, C-S and C-N) to demonstrate the enormous potential of a conjugately bridged Ir-Ni catalytic system, thus representing an alternative unimol. bimetallic strategy for photocatalytic Ni mediated cross-coupling reactions.
Organic Chemistry Frontiers published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C6H6N2O, Safety of 2-Methylbenzoic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia