Wang, Lihua published the artcileInclusion of guest materials in aqueous coordination network shells spontaneously generated by reacting 2,5-dimercapto-1,3,4-thiadiazole with nanoscale metallic silver, Recommanded Product: 5,9-Diaminobenzo[a]phenoxazin-7-ium acetate, the publication is RSC Advances (2014), 4(65), 34294-34302, database is CAplus.
Noble metal nanoparticles (NPs) are spontaneously enfolded by aqueous coordination networks generated by reacting 2,5-dimercapto-1,3,4-thiadiazole (DMcT) with Ag nanostructures in zero-oxidation state, and finally form novel hollow Au@Ag@infinite coordination polymers core-shell nanostructures (Au@Ag@void@ICPs). In this synthesis, DMcT mols. not only act as the bridging ligands but also directly oxidize Ag0 to Ag+ ions for the formation of amorphous DMcT-Ag ICPs. And, the sizes of the shell and void of Au@Ag@void@ICPs can be facilely tuned by modulating the amount of DMcT and the size ratio of Au@Ag NPs, resp. Due to the high structural tailorability of DMcT-Ag ICPs, multi-encapsulation of Au@Ag NPs with either small organic mols. or biol. macromols. (e.g., enzymes) can be achieved to fabricate multi-functional core-shell nanostructures. A case in point is that a highly sensitive biosensor of H2O2 with a wider detection window was constructed based on the prepared metal NPs-ICPs-enzyme composites and resonance Raman scattering. This study provides not only a new template for tailoring hollow core-shell nanomaterials but also a versatile platform for chem. (bio) sensing.
RSC Advances published new progress about 10510-54-0. 10510-54-0 belongs to catalysis-chemistry, auxiliary class Other Aromatic Heterocyclic,Salt,Amine,Inhibitor,Inhibitor, name is 5,9-Diaminobenzo[a]phenoxazin-7-ium acetate, and the molecular formula is 0, Recommanded Product: 5,9-Diaminobenzo[a]phenoxazin-7-ium acetate.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia