Wu, Haoran published the artcilePreparation of Copper Phosphate from Naturally Occurring Phytic Acid as an Advanced Catalyst for Oxidation of Aromatic Benzyl Compounds, Recommanded Product: Bis(4-fluorophenyl)methane, the publication is ACS Sustainable Chemistry & Engineering (2018), 6(11), 13670-13675, database is CAplus.
Both direct oxidation of aromatic benzyl compounds to aromatic ketones and utilization of naturally occurring chems. to prepare functional catalysts are highly attractive. Herein, copper phosphate was successfully synthesized by using naturally occurring phytic acid as the phosphorus source. The obtained copper phosphate showed excellent performance for the direct oxidation of aromatic benzyl compounds to aromatic ketones with N-hydroxyphthalimide (NHPI) as the radical promoter using O2 as the oxidant. Addnl., the synthesized copper phosphate was stable in the reaction system and could be used at least four cycles without considerable decrease in catalytic performance. This work provides a new way to prepare efficient heterogeneous catalysts using naturally occurring chems. for the highly efficient oxidation of aromatic benzyl compounds to aromatic ketones.
ACS Sustainable Chemistry & Engineering published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C15H14O3, Recommanded Product: Bis(4-fluorophenyl)methane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia