Frohn, Hermann-Josef’s team published research in Journal of Fluorine Chemistry in 125 | CAS: 1206-46-8

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Synthetic Route of 1206-46-8.

Frohn, Hermann-Josef published the artcileC6F5XeF, a versatile starting material in xenon-carbon chemistry, Synthetic Route of 1206-46-8, the publication is Journal of Fluorine Chemistry (2004), 125(6), 981-988, database is CAplus.

Arylxenon fluorides undergo substitution reactions to give sym. and asym. diarylxenons. The mols. ArFXeF (ArF = C6F5, 2,4,6-C6H2F3) with a more polar Xe-F bond than XeF2 are versatile starting materials for substitution reactions. Reaction of C6F5XeF (1) with ArF2Cd gave C6F5XeArF (2, 4), which, in case of ArF = 2,4,6-C6H2F3, upon symmetrization gave (2,4,6-C6H2F3)2Xe (5), the same result was obtained by reaction of 1 with C6F5SiF3. Applying C6F5BF2, with a higher F-affinity than the corresponding aryltrifluorosilane, in contrast gave the salt [C6F5Xe][ArFBF3]. Using the alkenyl and alkyl compounds CF2:CFSiMe3/[F], CF3SiMe3/[F], and Cd(CF3)2 in reactions with C6F5XeF, the perfluoroalkenyl or -alkyl transfer reagents were consumed without formation of corresponding xenon derivatives The formation of Xe(C6F5)2 in these reactions suggests the symmetrization of the corresponding vinylxenon intermediate; the unstable aryl-trifluoromethyl xenon afforded octafluorotoluene as coupling product.

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Synthetic Route of 1206-46-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia