Grohmann, Christoph’s team published research in Organic Letters in 14 | CAS: 1293990-73-4

Organic Letters published new progress about 1293990-73-4. 1293990-73-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is O-Pivaloylhydroxylamine trifluoromethanesulfonate, and the molecular formula is C6H12F3NO5S, Computed Properties of 1293990-73-4.

Grohmann, Christoph published the artcileRh[III]-Catalyzed Direct C-H Amination Using N-Chloroamines at Room Temperature, Computed Properties of 1293990-73-4, the publication is Organic Letters (2012), 14(2), 656-659, database is CAplus and MEDLINE.

An efficient Rh(III)-catalyzed direct C-H amination of N-pivaloyloxy benzamides with N-chloroamines proceeding at room temperature was achieved. The versatile directing group allows for selective mono- and diamination and can be readily converted to give valuable benzamide or aminoaniline derivatives, e.g., I. Mechanistic studies have been carried out to elucidate the reaction pathway.

Organic Letters published new progress about 1293990-73-4. 1293990-73-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is O-Pivaloylhydroxylamine trifluoromethanesulfonate, and the molecular formula is C6H12F3NO5S, Computed Properties of 1293990-73-4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia