Ikeda, Yoshihiko published the artcileStereoselective synthesis of (Z)- and (E)-1,3-alkadienes from aldehydes using organotitanium and lithium reagents, Recommanded Product: Allyldiphenylphosphine oxide, the publication is Tetrahedron (1987), 43(4), 723-30, database is CAplus.
[3-(Diphenylphosphino)allyl]titanium reagent generated easily from allyldiphenylphosphine (I) condenses with aldehydes to give (Z)-1,3-alkadienes in high regio- and stereoselectivity. In contrast, lithiated I oxide condenses with aldehydes to give (E)-1,3–alkadienes directly and stereoselectively in good yields. Similarly, lithiated (1-buten-3-yl)diphenylphosphine oxide condenses with aldehydes to give (E)-3-methyl-1,3-alkadienes.
Tetrahedron published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Recommanded Product: Allyldiphenylphosphine oxide.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia