Nishida, Masakazu published the artcileSynthesis of Polyfluoro Aromatic Ethers: A Facile Route Using Polyfluoroalkoxides Generated from Carbonyl and Trimethysilyl Compounds, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Inorganic Chemistry (1995), 34(24), 6085-92, database is CAplus.
The polyfluoro aromatic ethers C6F5CH2ORF [RF = CF3, C2F5, CH2CF3, CF(CF3)2, C(CF3)3, C(CF3)2C6F5, C(CF3)2OCH2CF3, C(C6F5)2CF3], 4-CF3CH2OC6F4CH2OCH2CF3, and C6F5CH2OCF2CF2OCH2C6F5 were synthesized from C6F5CH2Br in the presence of CsF by reaction with the perfluoro carbonyl compounds COF2, CF3C(O)F, C6F5COF, (C6F5)2CO, (CF3)2CO, and (COF)2; reaction with polyfluoro siloxanes CF3CH2OSi(CH3)3 and C6F5OSi(CH3)3; or reaction with polyfluoroalkoxides generated from the fluorinated silanes CF3Si(CH3)3, C6F5Si(CH3)3, and CF3CH2OSi(CH3)3 reacting with the carbonyl compounds listed above. Single-crystal X-ray anal. of C6F5CH2OC(C6F5)2CF3 was reported. Reactivities of the carbonyl substrates and the silicon-containing reagents are discussed as a function of the alkyl (aryl) substituents present.
Inorganic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia