Poliak, Peter published the artcileSubstitution and torsional effects on the energetics of homolytic N-H bond cleavage in diphenylamines, Application In Synthesis of 1821-27-8, the publication is Polymer Degradation and Stability (2015), 37-44, database is CAplus.
The systematic study of substituent effects and torsional deformation on the N-H bond dissociation enthalpies (BDE) in diphenylamine (DPA) and 33 mono-, 33 di- and 22 tetrasubstituted diphenylamines is presented. The DPA and its derivatives were studied by means of (U)B3LYP/6-311++G** quantum-chem. method. Calculated gas-phase bond dissociation enthalpies approximated from the total electronic energies are in very good agreement with available exptl. solution-phase data. The substitution in the ortho and para position(s) can considerably alter the N-H BDE. The largest N-H BDE decrease is caused by the hydrogen bond forming substituents (-OH, -NH2) in the ortho positions and strong electron-donating groups placed in the para positions. Therefore, the improvement of the DPA antioxidant effectiveness, i.e. N-H BDE decrease, can be accomplished by the substitution in ortho or para position(s). The changes in mutual aromatic rings orientation in DPA mol. and studied derivatives affect the N-H BDE values considerably (increase by up to 28 kJ mol-1). Hence, the mutual aromatic rings orientation alterations may induce neg. effect on the antioxidant ability of DPA based antioxidants. Presented results indicate that the deviations of the antioxidant activity in various solid-phase matrixes could have origin also in the mutual benzene ring orientation of the antioxidant mol.
Polymer Degradation and Stability published new progress about 1821-27-8. 1821-27-8 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Amine,Benzene, name is Bis(4-nitrophenyl)amine, and the molecular formula is C12H9N3O4, Application In Synthesis of 1821-27-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia