Schneider, Astrid’s team published research in Zeitschrift fuer Anorganische und Allgemeine Chemie in 627 | CAS: 22693-41-0

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Application of 2,4,6-Triisopropylbenzenethiol.

Schneider, Astrid published the artcileA thiolate-zinc complex with a Zn4O4 bicyclooctane framework, Application of 2,4,6-Triisopropylbenzenethiol, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (2001), 627(8), 1771-1774, database is CAplus.

The reaction of ZnEt2 with 2,4,6-triisopropylthiophenol (HSR*) and N-methyl-2-hydroxymethylimidazole (ImCH2OH) in MeOH yields the complex Zn4(SR*)4(ImCH2O)3(OMe) with terminal SR* and bridging ImCH2O and MeO ligands. The structure of its Zn4O4 framework is that of a bicyclo[2.2.2]octane with Zn and O at the two apices. Crystal data: triclinic, P1?, a = 15.293(3), b = 17.453(4), c = 18.894(4) ?, ¦Á = 74.24(3), ¦Â = 71.44(3), ¦Ã = 73.15(3)¡ã, V = 4485.2(2) ?3, Z = 2, ¦Ñc = 1.29 g/cm3, ¦Ì(MoK¦Á) = 1.32 mm-1, 6487 observed reflections with I > 2¦Ò(I), 901 refined parameters, R1 = 0.091, wR2 (all data) = 0.323.

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Application of 2,4,6-Triisopropylbenzenethiol.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia