Ding, Peipei published the artcileSynthesis of heterobinuclear Cu(II)-Ni(II) complex: Structure, CT-DNA interaction, hydrolytic function and antibacterial studies, HPLC of Formula: 140-28-3, the publication is Journal of Molecular Structure (2019), 836-843, database is CAplus.
A new benzyls pendant-armed macrobicyclic heterbinuclear Cu(II)-Ni(II) complex has been obtained by template-directed synthesis and characterized by elemental anal., IR spectra, electrospray mass spectra, and single crystal x-ray diffraction. The complex was bridged by two phenolic oxygens and an acetate radical, with the Cu(II)-Ni(II) distance of 2.9292(8) ?. The hydrolytic function, CT-DNA binding and antibacterial properties were also studied. The initial rate values for the hydrolysis of 4-nitrophenylphosphate to 4-nitrophenolate by the Cu(II)-Ni(II) complex was 1.33 ¡Á 10-5 s-1, and 104 times faster than that the spontaneous hydrolysis of the phosphate monoester. The complex shows a better binding property to CT-DNA and the intrinsic binding constant is 1.29 ¡Á 105 M-1. The Stern-Volmer constant is 1.25 ¡Á 105 M-1. The viscosity increased obviously with the increase of complex concentration, the results showed that the complex bind to DNA through intercalation mode, which was in accordance with the absorption and emission spectral studies. The antibacterial activities against E.coli was also investigated using the Gentamycinas reference system.
Journal of Molecular Structure published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C16H20N2, HPLC of Formula: 140-28-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia