Ohta, Shun published the artcileOxido-Bridged Di-, Tri-, and Tetra-Nuclear Iron Complexes Bearing Bis(trimethylsilyl)amide and Thiolate Ligands, Computed Properties of 22693-41-0, the publication is Inorganic Chemistry (2012), 51(4), 2645-2651, database is CAplus and MEDLINE.
Di-, tri-, and tetra-nuclear iron-oxido clusters with bis(trimethylsilyl)amide and thiolate ligands were synthesized from the reactions of Fe{N(SiMe3)2}2 (1) with one equiv of thiol HSR (R = C6H5 (Ph), 4-tBuC6H4, 2,6-Ph2C6H3 (Dpp), 2,4,6-iPr3C6H2 (Tip)) and subsequent treatment with O2. The trinuclear clusters [{(Me3Si)2N}Fe]3(¦Ì3-O){¦Ì-S(4-RC6H4)}3 (R = H (3a), tBu (3b)) were obtained from the reactions of 1 with HSPh or HS(4-tBuC6H4) and O2, while the authors isolated a tetranuclear cluster [{(Me3Si)2N}2Fe2(¦Ì-SDpp)]2(¦Ì3-O)2 (4) as crystals from an analogous reaction with HSDpp. Treatment of a tertrahydrofuran (THF) solution of 1 with HSTip and O2 gave dinuclear [{(Me3Si)2N}(TipS)(THF)Fe]2(¦Ì-O) (5). The mol. structures of these complexes were determined by x-ray crystallog. anal. Cyclic voltammograms of the mixed valent Fe(II)Fe(III)2 complexes 3a and 3b are also presented which show a single one-electron oxidation and a single one-electron reduction for each of the two complexes.
Inorganic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Computed Properties of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia