Qiu, Xu’s team published research in Chinese Journal of Chemistry in 39 | CAS: 1293990-73-4

Chinese Journal of Chemistry published new progress about 1293990-73-4. 1293990-73-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is O-Pivaloylhydroxylamine trifluoromethanesulfonate, and the molecular formula is C6H12F3NO5S, HPLC of Formula: 1293990-73-4.

Qiu, Xu published the artcileSelective Carbon-Carbon Bond Amination with Redox-Active Aminating Reagents: A Direct Approach to Anilines, HPLC of Formula: 1293990-73-4, the publication is Chinese Journal of Chemistry (2021), 39(11), 3011-3016, database is CAplus.

Herein, a novel method for the preparation of anilines ArNH2 (Ar = 4-methylphenyl, naphthalen-2-yl, 2H-1,3-benzodioxol-5-yl, etc.) from alkylarenes ArCH2CH3 via Schmidt-type rearrangement using redox-active amination reagents RONH2+R1.OTf (R = Ns, Ts, tert-butylcarbonyl; R1 = H, Me, i-Pr), which are easily prepared from hydroxylamines R1NHOH was reported. Primary amines ArNH2 and secondary amines ArNHR1 were prepared from corresponding alkylarenes or benzyl alcs. ArCH(OH)CH3 under mild conditions. Good compatibility and valuable applications of the transformation were also displayed.

Chinese Journal of Chemistry published new progress about 1293990-73-4. 1293990-73-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is O-Pivaloylhydroxylamine trifluoromethanesulfonate, and the molecular formula is C6H12F3NO5S, HPLC of Formula: 1293990-73-4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia