Shu, Xin published the artcileDirect synthesis of Fe(III) immobilized Zr-based metal-organic framework for aerobic oxidation reaction, Quality Control of 457-68-1, the publication is Applied Organometallic Chemistry (2017), 31(12), n/a, database is CAplus.
A Zr-based metal-organic framework with bipyridine units (UiO-67) I has been utilized for the immobilization of catalytically active iron species via a post-synthetic metalation method. UiO-67 bipyridine MOF I was synthesized through a simple solvothermal method and was shown to have a UiO-type structure. Post-synthetic metalation of UiO-67 MOF I was performed for the immobilization of the catalytically active FeCl3. FT-IR and EDX element map suggested that FeCl3 is coordinately bonded to the UiO-67 bipyridine framework. The synthesized UiO-67-FeCl3?II catalyst was used for the aerobic oxidation of alcs. such as 4-methoxybenzyl alc., 1,2,3,4-tetrahydronaphthalen-1-ol, thiophen-2-ylmethanol, etc. and benzylic compounds such as ethylbenzene, 9H-fluorene and (4-fluorophenyl)methane in the presence of mol. oxygen. In addition, the UiO-67-FeCl3?II catalyst can be reused as a solid heterogeneous catalyst without compromising its activity and selectivity.
Applied Organometallic Chemistry published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C19H14Cl2, Quality Control of 457-68-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia