Brownbridge, Peter’s team published research in Tetrahedron Letters in 25 | CAS: 19117-31-8

Tetrahedron Letters published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Application of N-(tert-Butyl)-S-phenylthiohydroxylamine.

Brownbridge, Peter published the artcileAmidinosulfenylation of alkenes, Application of N-(tert-Butyl)-S-phenylthiohydroxylamine, the publication is Tetrahedron Letters (1984), 25(34), 3759-62, database is CAplus.

Reaction of phenylsulfenamides PhSNR1R2 [R1R2 = (CH2)4, (CH2)2O(CH2)2; R1 = H, R2 = Me3C] with alkenes, e.g., cyclohexene, in the presence of nitriles RCN (R = Me, Me2CH, Ph) gave amidines, e.g., I (same R, R1, R2). CF3SO3H and Me3SiO3SCF3 containing a catalytic quantity of CF3SO3H were used as promoters. Use of unsym. alkenes gave Markovnikov regiochem. exclusively. The mechanism involved generation of an episulfonium ion followed by attack of the nitrile on the ion in a Ritter-type reaction.. In the absence of nitriles, amines, e.g., II, were formed.

Tetrahedron Letters published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Application of N-(tert-Butyl)-S-phenylthiohydroxylamine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia