Karatas, Yasar published the artcilePreparation and characterization of amine-terminated delafossite type oxide, CuMnO2-NH2, supported Pd (0) nanoparticles for the H2 generation from the methanolysis of ammonia-borane, COA of Formula: C6H17NO3Si, the publication is International Journal of Hydrogen Energy (2022), 47(36), 16036-16046, database is CAplus.
Among the cuprous metal oxides of the delafossite type, which are generally formulated as CuMO2 (M = Al, Cr, Fe, Ga, Mn), the most promising is the CuMnO2 structures. CuMnO2 material, named crednerite, is a very interesting delafossite derivative with potential applications in many fields, mainly catalyst, photoelectrochem. cells and multiferroic tools. Herein, we report fabrication, characterization, and application of amine-terminated CuMnO2 (CuMnO2-NH2) supported palladium nanoparticles (Pd/CuMnO2-NH2) as highly efficient and recyclable catalysts for the hydrogen production from the methanolysis of ammonia-borane (AB). The results of characterization using P-XRD, TEM, HRTEM, TEM-EDX, XPS, SEM, SEM-elemental mapping, and ICP-OES disclose that Pd (0) nanoparticles were well spread on the surface of CuMnO2-NH2 with a mean particle size of 3.91 ¡À 0.33 nm. Pd/CuMnO2-NH2 shows high catalytic activity in the methanolysis of AB with an initial turnover frequency of 146.68 min-1 at 25 ¡À 0.1¡ãC which is one of the highest values ever reported for AB methanolysis in the literature. Besides, the extreme stability of Pd/CuMnO2-NH2 takes it a recyclable heterogeneous catalyst in this catalytic conversion.
International Journal of Hydrogen Energy published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, COA of Formula: C6H17NO3Si.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia