Talvik, A. published the artcileThe inductive effect. III. The kinetics of the reaction of substituted benzoic acids with diphenyldiazomethane, Synthetic Route of 31719-76-3, the publication is Collection of Czechoslovak Chemical Communications (1964), 29(5), 1266-76, database is CAplus.
cf. CA 59, 9765h. The rate constants of the reaction of diphenyldiazomethane (I) with 19 derivatives of BzOH substituted in the m- and p-position were measured at 25¡ã. The substituents were groups of negligible mesomeric effect. The kinetics were followed by measurement of the polarographic wave height of I in 40% EtOH in the presence of 0.1M NaCl and an excess of BzOH derivative partially titrated with NaOH. The rate constants were in the range 0.28-0.83 l./mole sec.; the dependence of their logarithms on Hammett substituent coasts. is linear. The purely inductive effect is transmitted from the p-position of the C6H6 nucleus with a greater intensity than from the m-position; this result is in accord with findings of the preceding part of this series based on measurement of dissociation constants A table of rate constants is given. 32 references.
Collection of Czechoslovak Chemical Communications published new progress about 31719-76-3. 31719-76-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 4-(Phenoxymethyl)benzoic acid, and the molecular formula is C11H16BNO3, Synthetic Route of 31719-76-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia