Thuery, Pierre published the artcileUranyl-Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Crystal Growth & Design (2011), 11(1), 347-355, database is CAplus.
Six novel complexes formed under hydrothermal conditions by uranyl ions with three ligands comprising a rigid phenyl- or cyclohexyl-containing platform, and two to four acetate arms were obtained. trigonal nodes. 1,3,5-Benzenetriacetic acid (H3BTA) yielded [NMe4][UO2(BTA)]¡¤H2O (1), in which the structure-directing counterion induces a two-dimensional, bilayer-type structure different from that previously reported, with both the tris-chelating ligand and the metal ion as. Two complexes were obtained with 1,2-phenylenedioxydiacetic acid (H2PDDA), [UO2(PDDA)(H2O)] (2) and [H2DABCO][(UO2)2(PDDA)3]¡¤1.5H2O (3). Complex 2 is a simple, ribbon-like, 1-dimensional polymer, while 3 is a nanotubular assembly built around the H-bonded, structure-directing counterions. Three complexes were obtained with trans-1,2-diaminocyclohexane-N,N,N’,N’-tetraacetic acid (H4DCTA), a polyaminopolycarboxylic acid, with different bases, [UO2(H2DCTA)(H2O)2]¡¤H2O (4), [UO2(H2DCTA)(H2O)]¡¤1.5H2O (5), and [UO2Na(HDCTA)(H2O)] (6). The N atoms are not coordinated, both of them (4) or only one (5 and 6) being protonated, and the carboxylic/ate groups are monodentate, except for one chelating in 6 and one nonbonding in 4. These differences in bonding result in various assemblies, 1-dimensional in 4 and two-dimensional in 5 and 6. The layers in 5 are strongly corrugated, with the cyclohexyl groups pointing on either side, and their packing displays oval-shaped channels, while the layers in 6 are planar, with the cyclohexyl groups located on one side, and further assembled into dimeric units by the disordered Na ions. These are the 1st crystal structures of actinide ion complexes with both H2PDDA and H4DCTA.
Crystal Growth & Design published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H13NO2, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia