Ruhlandt-Senge, Karin’s team published research in Chemical Communications (Cambridge) in | CAS: 22693-41-0

Chemical Communications (Cambridge) published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Name: 2,4,6-Triisopropylbenzenethiol.

Ruhlandt-Senge, Karin published the artcileSynthesis and characterization of the first discrete potassium thiolates displaying three different coordination spheres at potassium in one molecule, Name: 2,4,6-Triisopropylbenzenethiol, the publication is Chemical Communications (Cambridge) (1996), 147-48, database is CAplus.

Potassium hydride reacts with HSC6H2Pri3-2,4,6 (HSR) in THF or THF-tmen (tmen = N,N,N’,N’-tetramethylethylenediamine) to afford the first discrete, hexameric potassium thiolates [{K(SR)}2{K(THF)(SR)}2{K(THF)2(SR)}2] and [{K(SR)}2{K(THF)(SR)}2{K(tmen)(SR)}2]¡¤THF, exhibiting an unusual box-shaped structure with three different coordination spheres for the three independent potassium atoms.

Chemical Communications (Cambridge) published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Name: 2,4,6-Triisopropylbenzenethiol.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia