Pohl, Siegfried published the artcileSyntheses and structures of transition metal thiolate complexes containing the new bis(tetramethylguanidine) ligand btmgp, Related Products of catalysis-chemistry, the publication is Inorganica Chimica Acta (2000), 311(1-2), 106-112, database is CAplus.
The syntheses, spectroscopic and structural characterizations of the 1st Fe and Cu thiolate guanidine complexes are described. Reactions of the neutral complexes [CuI(btmgp)] and [FeI2(btmgp)] [btmgp = 1,3-bis(N,N,N’,N’-tetramethylguanidino)propane] with different uni- and bi-dentate thiolate ions yield the three-coordinate complex [Cu(S-2,4,6-tBu3C6H2)(btmgp)] (1) and the four-coordinate complexes [Fe(S-2,4,6-iPr3C6H2)2(btmgp)] (2) and [Fe(SiMe2(C6H4S)2)(btmgp)] (3) resp. Starting with [Fe(N(SiMe3)2)2], btmgp and the dithiol SiMe2(C6H4SH)2, an alternative procedure for the preparation of 3 is reported, demonstrating a useful synthetic approach towards neutral, N/S mixed coordinated Fe(II) complexes. The x-ray structure analyses of 1–3 reveal trigonal planar (2N/1S) (1) and tetrahedral (2N/2S) (2, 3) coordination environments around the metal centers.
Inorganica Chimica Acta published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia