Nishida, Masakazu’s team published research in Journal of Fluorine Chemistry in 131 | CAS: 1206-46-8

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Synthetic Route of 1206-46-8.

Nishida, Masakazu published the artcileFormation of perfluorinated polyphenylenes by multiple pentafluorophenylation using C6F5Si(CH3)3, Synthetic Route of 1206-46-8, the publication is Journal of Fluorine Chemistry (2010), 131(12), 1314-1321, database is CAplus.

Pentafluorophenylation of perfluoroarenes with C6F5Si(CH3)3 was investigated by using NMR and MALDI-TOF-MS techniques. Successive multiple pentafluorophenylation easily occurred not only on the para-position but also on the ortho-positions to provide perfluorinated p-phenylene and m-phenylene compounds The perfluoroarenes having electron-withdrawing substituents provided oligo- to poly-(phenylene)s depending on the added amounts of C6F5Si(CH3)3, while the perfluoroarenes having electron-donor substituents gave H(C6F4)nF polymers produced from C6F5H, which was the decomposed product of C6F5Si(CH3)3.

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Synthetic Route of 1206-46-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia