Wang, Huamin published the artcileElectrochemical Oxidation Enables Regioselective and Scalable ¦Á-C(sp3)-H Acyloxylation of Sulfides, Application In Synthesis of 2051-95-8, the publication is Journal of the American Chemical Society (2021), 143(9), 3628-3637, database is CAplus and MEDLINE.
A highly selective, environmentally friendly, and scalable electrochem. protocol for the construction of ¦Á-acyloxy sulfides e.g., (p-tolylthio)methyl acetate, through the synergistic effect of self-assembly-induced C(sp3)-H/O-H cross-coupling, is reported. It features exceptionally broad substrate scope, high regioselectivity, gram-scale synthesis, construction of complex mols. e.g., I, and applicability to a variety of nucleophiles such as acetic acid, cyclohexanecarboxylic acid, benzoic acid, benzotriazole, etc. Moreover, the soft X-ray absorption technique and a series of control experiments have been utilized to demonstrate the pivotal role of the self-assembly of the substrates, which indeed is responsible for the excellent compatibility and precise control of high regioselectivity in electrochem. protocol.
Journal of the American Chemical Society published new progress about 2051-95-8. 2051-95-8 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ketone, name is 3-Benzoylpropionicacid, and the molecular formula is C9H10O4, Application In Synthesis of 2051-95-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia