Schmaderer, Harald’s team published research in Advanced Synthesis & Catalysis in 351 | CAS: 30670-30-5

Advanced Synthesis & Catalysis published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Schmaderer, Harald published the artcilePhotooxidation of benzyl alcohols with immobilized flavins, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Advanced Synthesis & Catalysis (2009), 351(1+2), 163-174, database is CAplus.

Benzyl alcs. I [X = OMe, H, CO2Na, CO2Me, CO2H] are oxidized cleanly and efficiently to the corresponding aldehydes II under irradiation using flavin photocatalysts, e.g., III [R1 = R2 = (CH2)2(CF2)7CF3; R1 = CH2CH2OMe, R2 = Me, (CH2)2(CF2)7CF3] and IV [R3 = H, Me, R4 = Ac; R3 = Me, R4 = C(:O)(CH2)14Me] and aerial oxygen as the terminal oxidant in homogeneous aqueous solution Turnover frequencies (TOF) of more than 800 h-1 and turnover numbers (TON) of up to 68 were obtained. Several flavin photocatalysts with fluorinated or hydrophobic aliphatic chains were immobilized on solid supports like fluorous silica gel, reversed phase silica gel or entrapped in polyethylene pellets. The catalytic efficiency of the heterogeneous photocatalysts was studied for the oxidation of different benzyl alcs. in water and compared to the analogous homogeneous reactions. Removal of the heterogeneous photocatalyst stops the reaction conversion immediately, which shows that the immobilized flavin is the catalytically active species. The immobilized catalysts are stable, retain their reactivity if compared to the corresponding homogeneous systems and are easily removed from the reaction mixture and reused. TOF of up to 26 h-1, TON of 280 and up to 3 reaction cycles without loss of activity are possible with the heterogeneous flavin photocatalysts.

Advanced Synthesis & Catalysis published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia