Henry, Ronald A.’s team published research in Journal of Organic Chemistry in 55 | CAS: 14707-75-6

Journal of Organic Chemistry published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Application In Synthesis of 14707-75-6.

Henry, Ronald A. published the artcileAnomalous reaction of pentafluorophenacyl bromide with hexamethylenetetramine. Structure of the product, Application In Synthesis of 14707-75-6, the publication is Journal of Organic Chemistry (1990), 55(6), 1796-801, database is CAplus.

The title compounds condense in CHCl3 to yield tetrafluorobenzotetraazatetracyclotetradecanone I (X = N), a reaction proposed to involve both an ortho-fluorine elimination and two Stevens type rearrangements. Structural assignment of the fluorescent product I (X = N) was based upon 1H, 13C, 19F, and 15N NMR spectra and a complete x-ray crystallog. determination Addnl. studies supported the proposed mechanism and allowed improvements and modifications of the Delepine reaction as applied to phenacyl halides and for the preparation of I (X = CBr, CNH2, CNO2).

Journal of Organic Chemistry published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Application In Synthesis of 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia