Nishiyama, Yoshitake published the artcileSynthesis of benzyl sulfides via substitution reaction at the sulfur of phosphinic acid thioesters, COA of Formula: C18H23OP, the publication is Chemical Communications (Cambridge, United Kingdom) (2020), 56(43), 5771-5774, database is CAplus and MEDLINE.
An ambident electrophilicity of phosphinic acid thioesters RSP(O)(R1)2 (R = Me, pent-4-en-1-yl, naphthalen-2-yl, thiophen-3-yl, etc.; R1 = n-Bu, cyclohexyl, 2-methylphenyl, etc.) is disclosed. Unexpected carbon-sulfur bond formation took place in the reaction between phosphinic acid thioesters and Grignard reagents R2MgCl (R2 = Bn, 1-phenylethyl, naphthalen-1-ylmethyl, etc.). The developed method for benzyl sulfides RSR2 has a wide substrate scope and was applicable for the synthesis of a drug analog.
Chemical Communications (Cambridge, United Kingdom) published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, COA of Formula: C18H23OP.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia