Wang, Chong’s team published research in Applied Catalysis, B: Environmental in 294 | CAS: 457-68-1

Applied Catalysis, B: Environmental published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C10H10O2, Product Details of C13H10F2.

Wang, Chong published the artcileBiomimetic donor-acceptor motifs in carbon nitrides: enhancing red-light photocatalytic selective oxidation by rational surface engineering, Product Details of C13H10F2, the publication is Applied Catalysis, B: Environmental (2021), 120259, database is CAplus.

Oxidation, especially selective oxidation by a heterogeneous catalyst with mol. oxygen, is a core technol. for the conversion of petrochem. feedstock to commodity chems. and pharmaceuticals. Existing catalytic approaches for efficient aerobic oxidation normally rely on the engagement of organometallic centers or transition-metal nanoparticles. In light of the necessity to develop sustainable production methodologies, multiple approaches for the metal-free polymeric carbon nitride (PCN) photocatalytic selective oxidation have been evaluated. However, the insufficient visible light optical absorption, poor charge-carriers separation and the weak driving force towards oxidation reaction impart a serious restriction on the efficiency and selectivity of the organic photosynthesis, especially under extended wavelength solar light irradiation Here, we report a surface engineering photochem. modification method to fabricate a donor-acceptor (D-A) functional carbon nitride photocatalyst (ECN) under ambient conditions. The well-developed D-A structure, preserved high crystallinity and enlarged ¦Ð-conjugation framework of the hybrid semiconductor-mol. ECN samples favor the improvement of the optical absorption, as well as the enhanced separation and migration of the photo-generated charge carriers. As a result, the obtained ECN photocatalysts exhibited remarkable enhancement in the photocatalytic aerobic oxidation of alcs., even under an extended light wavelength of 620 nm red-light irradiation The photocatalytic aerobic sulfides and sp3 C-H oxidation reactions were also considerably accelerated over ECN and may serve as a direct approach for the construction of value-added sulfoxide and ketone products.

Applied Catalysis, B: Environmental published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C10H10O2, Product Details of C13H10F2.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia