Matsuo, Jun-ichi published the artcileN-tert-Butylbenzenesulfenamide-catalyzed oxidation of alcohols to the corresponding carbonyl compounds with N-chlorosuccinimide, Safety of N-(tert-Butyl)-S-phenylthiohydroxylamine, the publication is Tetrahedron (2003), 59(35), 6739-6750, database is CAplus.
N-tert-Butylbenzenesulfenamide(I)-catalyzed oxidation of various primary and secondary alcs. to the corresponding aldehydes and ketones was performed using N-chlorosuccinimide (NCS). Alcs. containing other functional groups were also oxidized to aldehydes or ketones without damaging any of the functional groups present. Selective oxidation of primary hydroxy groups took place when diols were subjected to the I-catalyzed oxidation Mechanistic investigation suggested that the chlorination of I by NCS led to the formation of a key species, N-tert-butylbenzenesulfinimidoyl chloride, which oxidized the alcs. to the carbonyl products while regenerating the catalyst I.
Tetrahedron published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Safety of N-(tert-Butyl)-S-phenylthiohydroxylamine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia