Bernardi, Luca published the artcileOrganocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Chemical Communications (Cambridge, United Kingdom) (2012), 48(10), 1428-1430, database is CAplus and MEDLINE.
A new approach to additions of silicon nucleophiles to imines was developed. E.g., in presence of TBAB and PhONa, reaction of TMSCF3 and PhCH:NTs gave 97% PhCH(CF3)NHTs. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.
Chemical Communications (Cambridge, United Kingdom) published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia