Brownlie, I. T. published the artcileInhibited autoxidation of styrene. VI. Relative efficiencies and the kinetics for inhibition by N-aryl anilines- and N-alkylanilines, HPLC of Formula: 1821-27-8, the publication is Canadian Journal of Chemistry (1967), 45(20), 2419-25, database is CAplus.
The kinetics and D isotope effects for the N-aryl aniline- and N-alkylaniline-inhibited autoxidation of styrene indicate that the rate-controlling step for inhibition involves abstraction of the amino H by a peroxy radical. The rate constants for this reaction were correlated by means of the Hammett equation with the ¦Ò+ constants of the substituents for diphenylamines (¦Ñ = -0.89) and N-methylanilines (¦Ñ = -1.6). A numerical difference involving a factor of 2 between the simple kinetic expression applicable to most aromatic amine inhibitors and the expression applicable to most phenols and p-phenylenediamines is suggested. The important role played by the substrate in studies of inhibitor action is emphasized. 25 references.
Canadian Journal of Chemistry published new progress about 1821-27-8. 1821-27-8 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Amine,Benzene, name is Bis(4-nitrophenyl)amine, and the molecular formula is C12H9N3O4, HPLC of Formula: 1821-27-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia