Zhu, Yan-ping’s team published research in Organic Letters in 14 | CAS: 2909-77-5

Organic Letters published new progress about 2909-77-5. 2909-77-5 belongs to catalysis-chemistry, auxiliary class Amine,Benzene, name is 2,6-Diisopropyl-N,N-dimethylaniline, and the molecular formula is C38H74Cl2N2O4, Application of 2,6-Diisopropyl-N,N-dimethylaniline.

Zhu, Yan-ping published the artcileI2-CF3SO3H Synergistic Promoted sp3 C-H Bond Diarylation of Aromatic Ketones, Application of 2,6-Diisopropyl-N,N-dimethylaniline, the publication is Organic Letters (2012), 14(20), 5378-5381, database is CAplus and MEDLINE.

An I2-CF3SO3H synergistic promoted sp3 C-H bond diarylation protocol was developed for the synthesis of 2,2-bis(4-(dimethylamino)phenyl)-1-aryl ethanones. Thus, reacting R1COMe (R1 = Ph, 4-MeOC6H4, 2-thienyl, etc.) with R2C6H5 (R2 = NMe2, NEt2, NPr2, etc.) in the presence of I2/CF3SO3H/DMSO gave diarylketones I. The reaction performed well in the absence of any metal and ligand. It integrated three reactions with different mechanisms (iodination, Kornblum oxidation, and hydroarylation) in a single reactor.

Organic Letters published new progress about 2909-77-5. 2909-77-5 belongs to catalysis-chemistry, auxiliary class Amine,Benzene, name is 2,6-Diisopropyl-N,N-dimethylaniline, and the molecular formula is C38H74Cl2N2O4, Application of 2,6-Diisopropyl-N,N-dimethylaniline.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia