Jiang, Qing published the artcileIron-Facilitated Oxidative Radical Decarboxylative Cross-Coupling between ¦Á-Oxocarboxylic Acids and Acrylic Acids: An Approach to ¦Á,¦Â-Unsaturated Carbonyls, Product Details of C9H7NO4, the publication is Journal of Organic Chemistry (2015), 80(7), 3586-3596, database is CAplus and MEDLINE.
The first Fe-facilitated decarboxylative cross-coupling reaction between ¦Á-oxocarboxylic acids and acrylic acids in aqueous solution has been developed. This transformation is characterized by its wide substrate scope and good functional group compatibility utilizing inexpensive and easily accessible reagents, thus providing an efficient and expeditious approach to an important class of ¦Á,¦Â-unsaturated carbonyls frequently found in bioactive compounds The synthetic potential of the coupled products is also demonstrated in subsequent functionalization reactions. Preliminary mechanism studies suggest that a free radical pathway is involved in this process: the generation of an acyl radical from ¦Á-oxocarboxylic acid via the excision of carbon dioxide followed by the addition of an acyl radical to the ¦Á-position of the double bond in acrylic acid then delivers the ¦Á,¦Â-unsaturated carbonyl adduct through the extrusion of another carbon dioxide.
Journal of Organic Chemistry published new progress about 1772-76-5. 1772-76-5 belongs to catalysis-chemistry, auxiliary class Benzenes, name is (E)-3-(3-Nitrophenyl)acrylic acid, and the molecular formula is C9H7NO4, Product Details of C9H7NO4.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia