Harmjanz, M. published the artcileNovel synthetic pathways to neutral mixed-ligand iron-sulfur clusters, Application In Synthesis of 22693-41-0, the publication is Zeitschrift fuer Naturforschung, B: Chemical Sciences (1996), 51(7), 1040-1048, database is CAplus.
The reaction of [Fe(N(SiMe3)2)2] with thiols RSH, elemental S, and neutral ligands L with sulfur donor atoms (e.g. thiourea derivatives) gives [Fe4S4(SR)2L2] clusters in high yields. The structure of [Fe4S4(2,4,6-Pr3C6H2S)2(dpdmi)2] (dpdmi = diisopropyldimethylimidazolethione) was determined by x-ray crystallog. When [Fe4S4I4]2- is reacted with a large excess of PMePh2 or PMe2Ph, [Fe6S6I2(PMePh2)4] and [Fe6S6I2(PMe2Ph)4], resp., are obtained in nearly quant. yield. Basket-like structures of the [Fe6S6]2+ cores were detected by x-ray structure anal. While [Fe4S4(SR)4]2- clusters do not react with phosphines at ambient temperature, 2:2 functionalized species like [Fe4S4(SR)2(tmtu)2] (tmtu = tetramethylthiourea) lead to basket-type clusters [Fe6S6(SR)2(PR3)4].
Zeitschrift fuer Naturforschung, B: Chemical Sciences published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Application In Synthesis of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia