Koehling, Jonas published the artcileOxamates as 1,2-Diketone Equivalents: The Effect of Fluorine, HPLC of Formula: 421-49-8, the publication is ChemistrySelect (2021), 6(8), 1882-1886, database is CAplus.
In this paper, new fluorinated derivatives were presented, which were synthesized from selected fluorinated primary amines RFNH2 (RF=CH2CF3, CH2CHF2, CH2CF2CH3, CH(CF3)2, CH(CH3)CF3) or their hydrochlorides and Et oxalylchloride. Since oxamates was considered as 1,2 diketones, their properties, geometries, effective charges at oxygen and nitrogen and the pKa values for the N-H grouping were investigated . In two cases, the mol. structures was measured by XRD, observing almost planar arrangement of C2-N1-C3-C4 atoms. The effect of fluorine was discussed and compared with non-fluorinated oxamates. The effective charges were controlled by various alkyl substituents at nitrogen (branched or straight, fluorinated or non-fluorinated) and can open a new field, especially when fluorinated, for multiple applications in material sciences (surfaces) and biochem. systems (enzymes).
ChemistrySelect published new progress about 421-49-8. 421-49-8 belongs to catalysis-chemistry, auxiliary class Trifluoromethyl,Fluoride,Amine,Aliphatic hydrocarbon chain, name is 1,1,1-Trifluoropropan-2-amine, and the molecular formula is C3H6F3N, HPLC of Formula: 421-49-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia