Sadakiyo, Masaaki published the artcileDesign and Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks Based on Salt Inclusion, SDS of cas: 17351-62-1, the publication is Journal of the American Chemical Society (2014), 136(5), 1702-1705, database is CAplus and MEDLINE.
The authors demonstrate a metal-organic framework (MOF) design for the inclusion of hydroxide ions. Salt inclusion method was applied to an alk.-stable ZIF-8 (ZIF = zeolitic imidazolate framework) to introduce alkylammonium hydroxides as ionic carriers. Tetrabutylammonium salts are immobilized inside the pores by a hydrophobic interaction between the alkyl groups of the salt and the framework, which significantly increases the hydrophilicity of ZIF-8. Also, ZIF-8 including the salt exhibited a capacity for OH– ion exchange, implying that freely exchangeable OH– ions are present in the MOF. ZIF-8 containing OH– ions showed an ionic conductivity of 2.3 ¡Á 10-8 S cm-1 at 25¡ã, which is 4 orders of magnitude higher than that of the blank ZIF-8. This is the first example of an MOF-based hydroxide ion conductor.
Journal of the American Chemical Society published new progress about 17351-62-1. 17351-62-1 belongs to catalysis-chemistry, auxiliary class Salt,Amine, name is Tetrabutylammonium hydrogencarbonate, and the molecular formula is C17H37NO3, SDS of cas: 17351-62-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia