Benbow, John W.’s team published research in Tetrahedron Letters in 38 | CAS: 4141-48-4

Tetrahedron Letters published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Formula: C15H15OP.

Benbow, John W. published the artcileAn efficient route to functionalized dienes for decalin synthesis, Formula: C15H15OP, the publication is Tetrahedron Letters (1997), 38(23), 4017-4020, database is CAplus.

Reaction of the trimethylsilyl (TMS) enol ethers, e.g. I, derived from the conjugate addition of organo-copper reagents to 3,4-dimethylcyclopentenone with di-Me dioxirane (DMDO) leads to ¦Á-hydroxy ketones with predominantly the syn-Me orientation. Exposure of these systems to methanolic lead tetraacetate (Pb(OAc)4) delivers aldehydic esters which are homologated to the desired E-dienes, e.g. II, using Yamamoto’s allylic phosphine oxide reagent.

Tetrahedron Letters published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Formula: C15H15OP.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia