Babadzhanova, Lesya A.’s team published research in Journal of Fluorine Chemistry in 125 | CAS: 1206-46-8

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Application In Synthesis of 1206-46-8.

Babadzhanova, Lesya A. published the artcileThe synthesis of salts and esters of perfluorinated dithio- and thiocarboxylic acids from carbon disulfide and carbonyl sulfide reacting with RFSiMe3/F–, Application In Synthesis of 1206-46-8, the publication is Journal of Fluorine Chemistry (2004), 125(7), 1095-1098, database is CAplus.

Trimethyl(perfluoroalkyl)silanes react with carbonyl sulfide and carbon disulfide in the presence of fluoride ion to give salts and, after alkylation of the latter, esters of the corresponding perfluorinated thio- and dithiocarboxylic acids. Thus, reaction of Me3SiCF3 with [Me4N]F and CS2 in monoglyme at -60¡ã gave 98% tetramethylammonium trifluorodithioacetate which on alkylation with BuI in MeCN gave 95% Bu trifluorodithioacetate.

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Application In Synthesis of 1206-46-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia