Al-Awadi, Nouria A. published the artcileKinetics and mechanism of thermal gas-phase elimination of 2-aryloxyacetic acid, Synthetic Route of 1798-04-5, the publication is International Journal of Chemical Kinetics (2001), 33(10), 612-616, database is CAplus.
Rates of thermal gas-phase elimination of eleven 2-aryloxyacetic acid have been measured over a 45¡ãC temperature range for each compound Hammett correlation of the present kinetic data with the literature ¦Ò0 values of the given substituents gave a reaction ¦Ñ constant of 0.69 at 600 K; this is more than that for the gas-phase elimination parameter of 2-aryloxypropanoic acid (¦Ñ = 0.26) and consistent with a transition state with some charge separation, suggesting a partial formation of carbocation. The implications of this observation for the thermal gas-phase elimination of ¦Á-aryloxycarboxylic acids are considered.
International Journal of Chemical Kinetics published new progress about 1798-04-5. 1798-04-5 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(4-(tert-Butyl)phenoxy)acetic acid, and the molecular formula is C12H16O3, Synthetic Route of 1798-04-5.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia