Hughes, David L. published the artcileFive-coordinate complexes [MoH(SC6H2R3-2,4,6)3(PR’Ph2)] (R = Me or Pri, R’ = Me or Et) and their reactions with nitrogen donors. Crystal structures of [MoH(SC6H2Pri3-2,4,6)3(C5H5N)(PMe2Ph)], [MoH(NC5H4S-2)2(SC6H2Pri3-2,4,6)(PEtPh2)] and [PPh4][MoO(SC6H2Pri3-2,4,6)4], Product Details of C15H24S, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1995), 5-15, database is CAplus.
[MoH(SC6H2R3-2,4,6)3(PR’Ph2)] (1) (R = Me or Pri, R’ = Me or Et) were prepared by reaction of HSC6H2R3-2,4,6 with [MoH4(PR’Ph2)4] or trans-[Mo(N2)2(Pr’Ph2)4]. 1 (R = Pri, R’ = Me) reacted with N-donor ligands L (py, 3-Mepy, 3,5-Me2py or C3H3NS) to give [MoH(SC6H2Pri3-2,4,6)3L(PMePh2)] (2). The crystal structure of the analog [MoH(SC6H2Pri3-2,4,6)3(py)(PMe2Ph)] showed the compound to have a trigonal girdle of thiolate ligands with the pyridine and PMe2Ph ligands in essentially apical positions. Reaction of 1 (R = Pri, R’ = Et) with pySH-2 gave the seven-coordinate complex [MoH(SC 6H2Pri3-2,4,6)(pyS-2)2(PEtPh2)], shown by x-ray crystallog. to have an essentially pentagonal-pyramidal geometry with the hydride located in the equatorial plane. Spectroscopic data for the compounds are discussed in terms of their structures. 1 (R = Pri, R’ = Et) exchanges hydride for deuteride on treatment with deuterium gas in benzene at 20¡ã. Treatment of 1 (R = Pri, R’ = Me) in MeOH with LiBEt3H, followed by [PPh4]Cl, gave [PPh4][MoO(SC6H2Pri3-2,4,6)4], shown by x-ray crystallog. to have an anion with square-pyramidal geometry and an apical oxide-ligand.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Product Details of C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia