Zemtsov, Artem A.’s team published research in Journal of Fluorine Chemistry in 132 | CAS: 1206-46-8

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9NO6S, Recommanded Product: Trimethyl(perfluorophenyl)silane.

Zemtsov, Artem A. published the artcileReactions of fluorinated silanes with 2-nitrocinnamates, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Journal of Fluorine Chemistry (2011), 132(6), 378-381, database is CAplus.

The interaction of ¦Á-nitrocinnamates with Me3SiRf (Rf = CF3, C2F5, C6F5) promoted by NaOAc in DMF or by Bu4NOAc in CH2Cl2 was described. The reactions proceeded as conjugate addition of the resp. fluorinated carbanion at the C:C bond and afforded 3-aryl-2-nitrobutanoic acid Me esters (aryl = Ph, 4-MeOC6H4, 2-furyl) bearing a fluorinated substituent in good yields as diastereomeric mixtures in ratios of 1:1 to 1.6:1. Subsequent hydrogenation led to amino acid esters.

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9NO6S, Recommanded Product: Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia