Zhang, Jin published the artcileAn air-stable, well-defined palladium-BIAN-NHC chloro dimer: a fast-activating, highly efficient catalyst for cross-coupling, Computed Properties of 613-33-2, the publication is Chemical Communications (Cambridge, United Kingdom) (2022), 58(53), 7404-7407, database is CAplus and MEDLINE.
Authors report the synthesis, characterization and reactivity of an air-stable, well-defined acenaphthoimidazolylidene palladium-BIAN-NHC chloro dimer complex, [Pd(BIAN-IPr)(¦Ì-Cl)Cl]2. This rapidly activating catalyst merges the reactive properties of palladium chloro dimers, [Pd(NHC)(¦Ì-Cl)Cl]2, with the attractive structural features of the BIAN framework. [Pd(BIAN-IPr)(¦Ì-Cl)Cl]2 is the most reactive Pd(II)-NHC precatalyst discovered to date undergoing fast activation under both an inert atm. and aerobic conditions. The catalyst features bulky-yet-flexible sterics that render the C-H substituents closer to the metal center in combination with rapid dissociation to monomers and strong ¦Ò-donor properties. [Pd(BIAN-IPr)(¦Ì-Cl)Cl]2 should be considered as a catalyst for reactions using well-defined Pd(II)-NHCs.
Chemical Communications (Cambridge, United Kingdom) published new progress about 613-33-2. 613-33-2 belongs to catalysis-chemistry, auxiliary class Benzene, name is 4,4′-Dimethyldiphenyl, and the molecular formula is C20H40O2, Computed Properties of 613-33-2.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia