Kang, Kai published the artcileC(sp2)-C(sp2) Reductive Elimination from Well-Defined Diarylgold(III) Complexes, Product Details of C9H9F5Si, the publication is Organometallics (2017), 36(24), 4727-4740, database is CAplus.
Well-defined phosphine-ligated diarylgold(III) complexes cis-[Au(L)(ArF)(Ar’)(Cl)] were prepared and detailed kinetics of the C(sp2)-C(sp2) reductive elimination from these complexes were studied. The mechanism of the reductive elimination from complexes cis-[Au(L)(ArF)(Ar’)(Cl)] was further studied by theor. calculation The combination of exptl. and theor. results suggests that the biaryl reductive elimination from organogold(III) complexes cis-[Au(L)(ArF)(Ar’)(Cl)] proceeds through a concerted biaryl-forming pathway from the four-coordinated Au(III) metal center. These studies also disclose that the steric hindrance of the phosphine ligands plays a major role in promoting the biaryl-forming reductive elimination from diarylgold(III) complexes cis-[Au(L)(ArF)(Ar’)(Cl)], while electronic properties of these ligands have a much smaller effect. Furthermore, the complexes with more weakly electron-withdrawing aryl ligands undergo reductive elimination faster and the elimination rate is not sensitive to the polarity of the solvents.
Organometallics published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Product Details of C9H9F5Si.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia