Spaller, William C.’s team published research in Advanced Synthesis & Catalysis in 364 | CAS: 457-68-1

Advanced Synthesis & Catalysis published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C10H18O, Name: Bis(4-fluorophenyl)methane.

Spaller, William C. published the artcileTetrahydroxydiboron-Mediated Palladium-Catalyzed Deoxygenative Transfer Hydrogenation of Aryl Ketones, Name: Bis(4-fluorophenyl)methane, the publication is Advanced Synthesis & Catalysis (2022), 364(15), 2571-2575, database is CAplus.

A palladium-catalyzed deoxygenative transfer hydrogenation of ketones ArC(O)R (Ar = Ph, 4-phenylphenyl, naphthalen-2-yl, etc.: R = Me, Ph, cyclobutyl, etc.) using B2(OH)4 as the sole additive was described. Deuterium labeling experiments using B2(OD)4 show that the incorporated protons originate exclusively from the diboron reagent. Spectroscopic evidence implicates the intermediacy of a borate ester. A variety of aromatic ketones can be deoxygenated using this approach.

Advanced Synthesis & Catalysis published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C10H18O, Name: Bis(4-fluorophenyl)methane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia