Sun, Lixin published the artcileCopolymerization of ethylene and butadiene with supported titanium catalyst, Application In Synthesis of 312-40-3, the publication is Journal of Polymer Science, Part B: Polymer Physics (1988), 26(10), 2113-26, database is CAplus.
The copolymerization of ethylene and butadiene with a supported titanium catalyst (TiCl4/MgCl2/Et benzoate/Ph2SiCl2/AlEt3) was described. The resulting products were characterized by IR, 13C NMR, x-ray diffraction, differential thermal anal., electron microscopy, and solvent extraction The butadiene units were substantially in trans-1,4-configuration and blocked sequences. Both ethylene and butadiene blocks formed crystalline phases. The presence of unsaturated bonds made it possible to graft Me methacrylate and maleic anhydride. The influences of monomer composition, temperature, Al/Ti ratio, catalyst concentration, and solvents on the copolymerization were investigated.
Journal of Polymer Science, Part B: Polymer Physics published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C6H3ClFNO2, Application In Synthesis of 312-40-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia