Hesp, Kevin D. published the artcilePalladium-Catalyzed Mono-¦Á-arylation of Acetone with Aryl Halides and Tosylates, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, the publication is Journal of the American Chemical Society (2011), 133(14), 5194-5197, database is CAplus and MEDLINE.
The first example of selective Pd-catalyzed mono-¦Á-arylation of acetone employing aryl chlorides, bromides, iodides, and tosylates is reported. The use of appropriately designed P,N-ligands proved to be the key to controlling the reactivity and selectivity. The reaction affords good yields with substrates containing a range of functional groups at modest Pd loadings using Cs2CO3 as the base and employing acetone as both a reagent and the solvent.
Journal of the American Chemical Society published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia