Korlyukov, Alexander A. published the artcileSi-Fluoro substituted quasisilatranes (N¡úSi) FYSi(OCH2CH2)2NR, Category: catalysis-chemistry, the publication is Journal of Organometallic Chemistry (2009), 694(5), 607-615, database is CAplus.
The reaction of fluorosilanes XYSiF2 (X = Y = F; X = F, Y = Ph; X = Ph, Y = Me) with diethanolamines and their O-trimethylsilyl derivatives affords novel Si-fluoro substituted quasisilatranes 3, 5 and 9. These compounds were characterized by the multinuclear NMR spectroscopy and x-ray diffraction anal. Exptl. and theor. calculated electron d. distribution functions in crystal structure of 9 have shown that the N ¡ú Si coordination bond corresponds to polar bond with pronounced ionic contribution. Calculated N ¡ú Si bond order in the compound 9 does not exceed 1/3 of the normal Si-N bond. A strong N ¡ú Si coordination bond exists in compounds 3, 5 and 9 the length of which varies in the range 1.98-2.175 ?.
Journal of Organometallic Chemistry published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia