Biju, Vasudevanpillai published the artcileIntermittent Single-Molecule Interfacial Electron Transfer Dynamics, Synthetic Route of 10510-54-0, the publication is Journal of the American Chemical Society (2004), 126(30), 9374-9381, database is CAplus and MEDLINE.
The authors report on single-mol. studies of photosensitized interfacial electron transfer (ET) processes in Coumarin 343 (C343)-TiO2 nanoparticles (NP) and Cresyl Violet (CV+)-TiO2 NP systems, using time-correlated single-photon counting coupled with scanning confocal fluorescence microscopy. Fluorescence intensity trajectories of individual dye mols. adsorbed on a semiconductor NP surface showed fluorescence fluctuations and blinking, with time constants distributed from milliseconds to seconds. The fluorescence fluctuation dynamics were found to be inhomogeneous from mol. to mol. and from time to time, showing significant static and dynamic disorders in the interfacial ET reaction dynamics. The authors attribute fluorescence fluctuations to the interfacial ET reaction rate fluctuations, associating redox reactivity intermittency with the fluctuations of mol.-TiO2 electronic and Franck-Condon coupling. Intermittent interfacial ET dynamics of individual mols. could be characteristic of a surface chem. reaction strongly involved with and regulated by mol.-surface interactions. The intermittent interfacial reaction dynamics that likely occur among single mols. in other interfacial and surface chem. processes can typically be observed by single-mol. studies but not by conventional ensemble-averaged experiments
Journal of the American Chemical Society published new progress about 10510-54-0. 10510-54-0 belongs to catalysis-chemistry, auxiliary class Other Aromatic Heterocyclic,Salt,Amine,Inhibitor,Inhibitor, name is 5,9-Diaminobenzo[a]phenoxazin-7-ium acetate, and the molecular formula is C18H15N3O3, Synthetic Route of 10510-54-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia