Dewanji, Abhishek published the artcileC-F Activation in Perfluorinated Arenes with Isonitriles under UV-Light Irradiation, Category: catalysis-chemistry, the publication is Chemistry – A European Journal (2015), 21(35), 12295-12298, database is CAplus and MEDLINE.
The aryl and alkyl isonitriles efficiently activated the strong C-F bond in perfluoroarenes by simple UV irradiation under mild conditions. Reactions proceeded by formal direct insertion of the isonitrile into the C-F bond without any transition metal. Activation occurs at arene C-F bonds whereas aliphatic C-F bonds remain unreacted. For selected perfluoroarenes C-F activation occurred with high regioselectivity and resulting imidoyl fluorides were transformed into other valuable compounds Theor. studies gave insights into the reaction mechanism.
Chemistry – A European Journal published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia