Rachor, Simon G. published the artcileSynthesis, Reactivity, and Bonding of Gold(I) Fluorido-Phosphine Complexes, Related Products of catalysis-chemistry, the publication is Inorganic Chemistry (2022), 61(1), 357-367, database is CAplus and MEDLINE.
Au(I) fluorido complexes with phosphine ligands were synthesized from their resp. iodo precursors. The bonding situation in comparison between complexes bearing phosphines and N-heterocyclic carbenes (NHCs) was explored quantum-chem., obtaining similar results for both. Calculations of the 19F NMR chem. shifts match the exptl. values well, including the ?40 ppm low-field shifts for the phosphine complexes compared to the NHC complexes, in spite of similar neg. charges on F. The reactivity of the highly H2O-sensitive Au(I) fluorido complexes was studied, resulting in substitution at the metal using trimethylsilyl reagents. The compounds studied were characterized using NMR as well as x-ray diffraction methods.
Inorganic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia