Kafka, Zdenek published the artcileNitrogen compounds of adamontane. IX. Preparation and reactions of nitrogen analogs of adamantane, Recommanded Product: 1,3,5-Triazaadamantan-7-amine, the publication is Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, D: Technologie Paliv (1976), 127-57, database is CAplus.
Substituted 1-aza-, 1,3-diaza-, 1,3,5-triazaadamantanes (I), and 1,3-diazaadamantan-6-ols (II) and their derivatives were prepared and characterized by ir, gas chromatog., and paper chromatog. Reaction of Me2CO, AcONH4, and aromatic aldehydes gave tetrasubstituted 3,7-diazabicyclo[3.3.1]nonan-9-ones, which gave 1,3-diazaadamantan-6-ones on boiling with paraformaldehyde. These compounds were hydrogenated to tetracyclohexyl derivatives of II over Raney Ni. The 7-nitro derivative of I was prepared and reduced to the 7-amino derivative with Zn or Al in alk. medium. The latter compound gave 7-halo compounds and other derivatives Aromatic aldehydes and the 7-amino derivative of I gave aldimines, which were hydrogenated to secondary amines. I was stable in mineral acids but not in a reducing acid medium. Reductive methylation of the 7-amino derivative of I gave 7-alkylamino derivative The nitrile of N-(1,3,5-triaza-1-adamantyl)aminoacetic acid, prepared by cyanomethylation, was reduced to the 7-(aminomethyl)amino derivative with LiAlH4. Partial hydrogenation of the 7-nitro derivative of I gave the 7-hydroxylamino derivative, which with hexamethyldisilazane gave the trimethylsilyl derivative Oxidation with H2O2 or ozonization of the 7-nitro derivative of I gave the N-oxide.
Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, D: Technologie Paliv published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Recommanded Product: 1,3,5-Triazaadamantan-7-amine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia