Sauer, Scott J. published the artcileDirect Carbon-Carbon Bond Formation via Reductive Soft Enolization: A Kinetically Controlled syn-Aldol Addition of ¦Á-Halo Thioesters and Enolizable Aldehydes, Related Products of catalysis-chemistry, the publication is Journal of the American Chemical Society (2010), 132(40), 13997-13999, database is CAplus and MEDLINE.
The direct addition of enolizable aldehydes and ¦Á-halo thioesters to produce ¦Â-hydroxy thioesters enabled by reductive soft enolization is reported. The transformation is operationally simple and efficient and has the unusual feature of giving high syn-selectivity, which is the opposite of that produced for (thio)esters under conventional conditions. Moreover, excellent diastereoselectivity results when a chiral nonracemic ¦Á-hydroxy aldehyde derivative is used.
Journal of the American Chemical Society published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia